Arsenic vs Antimony
Both are metalloids, so they share the same broad chemistry.
The differences in plain English
- They sit in the same column, group 15, so they have the same number of outer electrons and react in similar ways; the heavier one, Antimony, is usually the more reactive of the two if they are metals, and the less reactive if they are non-metals.
- Both are solids at room temperature.
- Antimony is denser, about 17 per cent more than Arsenic (6.697 against 5.727 g/cm³).
- An atom of Antimony is about 63 per cent heavier than an atom of Arsenic (121.76 u against 74.92 u).
- Arsenic pulls electrons more strongly in a bond (electronegativity 2.18 against 2.05).
Side by side
| Arsenic | Antimony | |
|---|---|---|
| Atomic number | 33 | 51 |
| Symbol | As | Sb |
| Family | Metalloid | Metalloid |
| Group / period | 15 / 4 | 15 / 5 |
| State at room temperature | Solid | Solid |
| Atomic mass | 74.922 u | 121.760 u |
| Density | 5.727 g/cm³ | 6.697 g/cm³ |
| Melting point | – | 631 °C |
| Boiling point | – | 1635 °C |
| Electronegativity | 2.18 | 2.05 |
| First ionisation energy | 947 kJ/mol | 834 kJ/mol |
| Electron configuration | [Ar] 3d10 4s2 4p3 | [Kr] 4d10 5s2 5p3 |
| Discovered by | Bronze Age | unknown, before 3000 BC |
Arsenic
Few elements carry as much reputation as arsenic. It was the classic murder weapon of Renaissance courts and Victorian novels, tasteless and once impossible to detect. Yet it has also been a medicine for over two thousand years, a pigment that coloured wallpapers and paintings, and today a licensed drug for a form of leukaemia. Its compound with gallium is a high-performance semiconductor inside almost every mobile phone.
- At normal air pressure arsenic never becomes a liquid: it goes straight from solid to vapour at about 615 °C.
- Copper alloyed with arsenic was in use before tin bronze, so arsenic metallurgy is older than the Bronze Age name suggests.
Antimony
Antimony sits on the staircase of metalloids that separates metals from non-metals. It looks like a metal, silvery and shiny, but it is brittle, conducts electricity poorly and behaves chemically like a cross between a metal and a non-metal. That in-between character has made it useful in surprising ways for thousands of years.
- Stibnite, antimony's main ore, was ground up and used as kohl eye make-up in ancient Egypt.
- Antimony is one of the few substances that expands when it freezes, a property shared with water, bismuth and gallium.
Colour the bubbles by density or melting point and the difference jumps out.
More comparisons
Data from Periodic-Table-JSON (CC BY-SA); temperatures rounded to the nearest degree. Written by Anthony.